Silicon Lattice & Doping Silicon With Boron & Phosporous

Silicon Lattice & Doping Silicon With Boron & Phosporous
Silicon Lattice & Doping Silicon With Boron & Phosporous
Silicon Lattice & Doping Silicon With Boron & Phosporous

 A graphic representing a two dimensional silicon lattice. The silicon atoms and interatomic covalent bonds are shown and labelled.

A graphic representing the doping of silicon with boron atoms. The boron atoms have one less valence electron, creating a p-type semiconductor.

A graphic representing the doping of silicon with phosphorus atoms. The phosphorus atoms have an extra valence electron, creating an n-type semiconductor.


N-type Semiconductor Basics:

In order for our silicon crystal to conduct electricity, we need to introduce an impurity atom such as Arsenic, Antimony or Phosphorus into the crystalline structure making it extrinsic (impurities are added). These atoms have five outer electrons in their outermost orbital to share with neighbouring atoms and are commonly called “Pentavalent” impurities.

This allows four out of the five orbital electrons to bond with its neighbouring silicon atoms leaving one “free electron” to become mobile when an electrical voltage is applied (electron flow). As each impurity atom “donates” one electron, pentavalent atoms are generally known as “donors”.

Antimony (symbol Sb) or Phosphorus (symbol P), are frequently used as a pentavalent additive to the silicon as they have 51 electrons arranged in five shells around their nucleus with the outermost orbital having five electrons. The resulting semiconductor basics material has an excess of current-carrying electrons, each with a negative charge, and is therefore referred to as an N-type material with the electrons called “Majority Carriers” while the resulting holes are called “Minority Carriers”.

When stimulated by an external power source, the electrons freed from the silicon atoms by this stimulation are quickly replaced by the free electrons available from the doped Antimony atoms. But this action still leaves an extra electron (the freed electron) floating around the doped crystal making it negatively charged.

Then a semiconductor material is classed as N-type when its donor density is greater than its acceptor density, in other words, it has more electrons than holes thereby creating a negative pole.

P-Type Semiconductor Basics:

If we go the other way, and introduce a “Trivalent” (3-electron) impurity into the crystalline structure, such as Aluminium, Boron or Indium, which have only three valence electrons available in their outermost orbital, the fourth closed bond cannot be formed. Therefore, a complete connection is not possible, giving the semiconductor material an abundance of positively charged carriers known as holes in the structure of the crystal where electrons are effectively missing.

As there is now a hole in the silicon crystal, a neighbouring electron is attracted to it and will try to move into the hole to fill it. However, the electron filling the hole leaves another hole behind it as it moves. This in turn attracts another electron which in turn creates another hole behind it, and so forth giving the appearance that the holes are moving as a positive charge through the crystal structure (conventional current flow).

This movement of holes results in a shortage of electrons in the silicon turning the entire doped crystal into a positive pole. As each impurity atom generates a hole, trivalent impurities are generally known as “Acceptors” as they are continually “accepting” extra or free electrons.

Boron (symbol B) is commonly used as a trivalent additive as it has only five electrons arranged in three shells around its nucleus with the outermost orbital having only three electrons. The doping of Boron atoms causes conduction to consist mainly of positive charge carriers resulting in a P-type material with the positive holes being called “Majority Carriers” while the free electrons are called “Minority Carriers”.

Then a semiconductor basics material is classed as P-type when its acceptor density is greater than its donor density. Therefore, a P-type semiconductor has more holes than electrons.

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